Frankie, I'm only new to all this myself but from what I have read on these forums, a 100Ah battery, in good condition, and fully charged, should give you at least a day maybe 2 running the 70l Evakool fridge. Of course, that depends what you put in it and how often you open it etc. With solar and a genny as backup, I don't think you will have too many problems with the fridge. I would hook the fridge to the van battery of a night then no problems with starting the car the next day.
Can you wire the 2nd battery in the van as you don't have space in the Terracan?
LED lights will use less juice but again I don't think you need to worry.
Have a great trip.