Hey Goose ,
If it is a internal door, external door eg laundry make sure you prime the underneath edge before fitting ,all gloss enamels will yellow with age your other doors probally started out white but have yellowed you will not stop it using enamel ,but in saying that enamel will always give you a glossier finish then Acrylic most painters use acrylic in new houses these days but i still prefer enamel , as others have said just slice a bit of the old door and slip down to a paint shop or bunnings and they will scan it for you (free) and you should get a colour that is that close it will not matter , i would give a local painter a call and see if they can paint it for you might cost $150 or so but by the time you muck around and buy primer ,undercoat ,gloss enamel ,a brush , a roller , sandpaper , a bit of turps and the pain of doing it and probally still will not look as good as a professional finish is it worth it ? my opinion anyway
cheers Jason